Whisk in the all-purpose flour, baking powder, baking soda, and hot coffee just until smooth and combined. Do not overmix.
Pour the batter into the prepared pan and smooth the top with a spatula. Bake at 180°C (350°F) for 30 minutes, or until a toothpick inserted into the center comes out clean. Cool completely in the pan on a wire rack before frosting.
Make the chocolate frosting & assembly:
In a large bowl, combine the softened butter, powdered sugar, heavy cream, cooled, melted dark chocolate, kosher salt, vanilla extract, and sifted cocoa powder.
Beat on low speed with an electric hand mixer until combined, then beat on medium-high speed for 3 minutes until fluffy.
Spread the frosting over the cooled cake with an offset spatula and serve.
Notes
Hot Coffee Replacement: Hot coffee blooms the cocoa powder for maximum chocolate flavor without leaving any coffee taste. You can substitute equal amounts of boiling water or decaf hot coffee if preferred.
Cool the Melted Chocolate: Ensure the melted dark chocolate cools to room temperature before beating it into the buttercream. Warm chocolate will melt the butter and cause the frosting to separate.
Measuring Flour: Spoon flour into your measuring cup and level it off with the back of a knife, or use a kitchen scale for best results. Packing flour directly from the bag will yield a heavy, dense cake.
Cocoa Powder: Dutch-processed cocoa yields a richer flavor and darker color, but natural unsweetened cocoa powder works as a direct 1:1 substitute.
Room Temperature Ingredients: Use room-temperature egg and buttermilk so the wet batter emulsifies smoothly without separating.
Buttermilk Substitute: Combine ½ cup of whole milk with ½ tablespoon of lemon juice or white vinegar. Let it sit for 5 minutes before adding to the batter.
Serving Tip: Serve this cake at room temperature so the fudgy dark chocolate frosting remains soft, silky, and easy to slice.